TY - BOOK AU - Sigel,Astrid AU - Sigel,Helmut AU - Sigel,Roland K.O. TI - Metal-carbon bonds in enzymes and cofactors T2 - Metal ions in life sciences, SN - 9781847559159 AV - MED QP601.7 M47 PY - 2009/// CY - Cambridge PB - RSC KW - Metalloenzymes KW - Coenzymes KW - Organometallic compounds KW - Vitamin B12 KW - Organometallic Compounds KW - Multienzyme Complexes KW - Oxidoreductases KW - Vitamin B 12 KW - Cofaktor KW - Enzym KW - Metallorganische Verbindungen N1 - Organometallic chemistry of B₁₂ coenzymes -- Cobalamin- and corrinoid-dependent enzymes -- Nickel-alkyl bond formation in the active site of methyl-coenzyme M reductase -- Nickel-carbon bonds in acetyl-coenzyme a synthases/carbon monoxide dehydrogenases -- Structure and function of [NiFe]-hydro-genases -- Carbon monoxide and cyanide ligands in the active site of [FeFe]-hydrogenases -- Carbon monoxide as intrinsic ligand to iron in the active site of [Fe]-hydrogenase -- Dual role of heme as cofactor and substrate in the biosynthesis of carbon monoxide -- Copper-carbon bonds in mechanistic and structural probing of proteins as well as in situations where copper is a catalytic or receptor site -- Interaction of cyanide with enzymes containing vanadium, manganese, non-heme iron, and zinc -- Reaction mechanism of the molybdenum hydroxylase xanthine oxidoreductase: evidence against the formation of intermediates having metal-carbon bonds UR - http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&doc_number=017618346&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA UR - http://www.loc.gov/catdir/enhancements/fy1110/2011286706-b.html UR - http://www.loc.gov/catdir/enhancements/fy1110/2011286706-d.html ER -